Constructing Explicit Magnetic Analogies for the Dynamics of Glass Forming Liquids

Jacob D. Stevenson, Aleksandra M. Walczak, Randall W. Hall, Peter G. Wolynes

Research output: Contribution to journalArticlepeer-review

Abstract

By defining a spatially varying replica overlap parameter for a supercooled liquid referenced to an ensemble of fiducial liquid state configurations, we explicitly construct a constrained replica free energy functional that maps directly onto an Ising Hamiltonian with both random fields and random interactions whose statistics depend on the liquid structure. Renormalization group results for random magnets when combined with these statistics for the Lennard-Jones glass suggest that discontinuous replica symmetry breaking would occur if a liquid with short range interactions could be equilibrated at a sufficiently low temperature where its mean field configurational entropy would vanish, even though the system strictly retains a finite configurational entropy.

Original languageAmerican English
Article number194505
Pages (from-to)194505
JournalThe Journal of Chemical Physics
Volume129
Issue number19
DOIs
StatePublished - Nov 21 2008
Externally publishedYes

Funding

The authors thank David Sherrington for enjoyable discussions. Calculations were performed on computational facilities provided by LSU ( http://www.hpc.lsu.edu ) and the Louisiana Optical Network Initiative ( http://www.loni.org ). Support from NSF under Grant No. CHE0317017 and NIH under Grant No. 5R01GM44557 is gratefully acknowledged.

FundersFunder number
National Science FoundationCHE0317017
National Institutes of Health
National Institute of General Medical SciencesR01GM044557

    ASJC Scopus Subject Areas

    • General Physics and Astronomy
    • Physical and Theoretical Chemistry

    Keywords

    • Free Energy
    • Mean Field Theory
    • Entropy
    • Magnetic Liquids
    • Magnets

    Disciplines

    • Chemistry
    • Physics

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