Abstract
By defining a spatially varying replica overlap parameter for a supercooled liquid referenced to an ensemble of fiducial liquid state configurations, we explicitly construct a constrained replica free energy functional that maps directly onto an Ising Hamiltonian with both random fields and random interactions whose statistics depend on the liquid structure. Renormalization group results for random magnets when combined with these statistics for the Lennard-Jones glass suggest that discontinuous replica symmetry breaking would occur if a liquid with short range interactions could be equilibrated at a sufficiently low temperature where its mean field configurational entropy would vanish, even though the system strictly retains a finite configurational entropy.
| Original language | American English |
|---|---|
| Article number | 194505 |
| Pages (from-to) | 194505 |
| Journal | The Journal of Chemical Physics |
| Volume | 129 |
| Issue number | 19 |
| DOIs | |
| State | Published - Nov 21 2008 |
| Externally published | Yes |
Funding
The authors thank David Sherrington for enjoyable discussions. Calculations were performed on computational facilities provided by LSU ( http://www.hpc.lsu.edu ) and the Louisiana Optical Network Initiative ( http://www.loni.org ). Support from NSF under Grant No. CHE0317017 and NIH under Grant No. 5R01GM44557 is gratefully acknowledged.
| Funders | Funder number |
|---|---|
| National Science Foundation | CHE0317017 |
| National Institutes of Health | |
| National Institute of General Medical Sciences | R01GM044557 |
ASJC Scopus Subject Areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry
Keywords
- Free Energy
- Mean Field Theory
- Entropy
- Magnetic Liquids
- Magnets
Disciplines
- Chemistry
- Physics